For the equilibrium $A_{(g)} \rightleftharpoons B_{(g)}$,$\Delta H$ is $-40 \ kJ/mol$. If the ratio of the activation energies of the forward $(E_f)$ and reverse $(E_b)$ reactions is $\frac{2}{3}$,then:

  • A
    $E_f = 80 \ kJ/mol; E_b = 120 \ kJ/mol$
  • B
    $E_f = 60 \ kJ/mol; E_b = 100 \ kJ/mol$
  • C
    $E_f = 30 \ kJ/mol; E_b = 70 \ kJ/mol$
  • D
    $E_f = 70 \ kJ/mol; E_b = 30 \ kJ/mol$

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The decomposition of $N_2O$ into $N_2$ and $O_2$ in the presence of argon follows first-order kinetics. If the rate constant is given by $K = 5.0 \times 10^{11} \, e^{-2000/T}$,what is the activation energy of the reaction?

Subtract $(i)$ $\ln \, k_1 = - \frac{E_a}{R T_1} + \ln A$ and $(ii)$ $\ln \, k_2 = - \frac{E_a}{R T_2} + \ln A$ and write the resulting equation.

The rate constant of a reaction depends upon

Which equation is true to calculate the energy of activation,if the rate of reaction is doubled by increasing temperature from $T_1 \ K$ to $T_2 \ K$?

Consider the following statements:
$(i)$ Increase in concentration of reactant increases the rate of a zero order reaction
$(ii)$ Rate constant $k$ is equal to $A$ if $E_a = 0$
$(iii)$ Rate constant $k$ is equal to $A$ if $E_a = \infty$
$(iv)$ $\log_e k$ vs $T$ is a straight line
$(v)$ $\log_e k$ vs $1/T$ is a straight line
Which of the following statements are correct?

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